cis-(Di-2-pyridylamine-κ2 N 2,N 2′)bis(thiocyanato-κS)platinum(II)
نویسنده
چکیده
In the title complex, [Pt(NCS)(2)(C(10)H(9)N(3))], the Pt(II) ion is four-coordinated in a distorted square-planar environment by the two pyridine N atoms of the chelating di-2-pyridyl-amine (dpa) ligand and two mutually cis S atoms from two linear thio-cyanate anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 30.8 (4)°. In the crystal, the complex mol-ecules are stacked in columns along the a axis and are connected by inter-molecular N-H⋯N hydrogen bonds, forming supra-molecular chains along the b axis.
منابع مشابه
Bis(di-2-pyridylamine-κ2 N,N′)bis(thiocyanato-κN)nickel(II)
The mononuclear neutral title complex, [Ni(NCS)(2)(C(10)H(9)N(3))(2)], shows a cis-octa-hedral geometry around the Ni(II) ion, formed by two chelating di-2-pyridyl-amine (Hdpa) ligands and two thio-cyanate anions. Both amine H atoms are involved in N-H⋯S hydrogen bonding, resulting in the formation of layers of inter-linked mol-ecules parallel to the ab plane, which are further held together by...
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